BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The isolation and crystal structure of {Li·(H2O)2·[OP(NMe2)3]}22+·2Cl–: a (LiO)2 ring compound with bridging neutral oxygen (hexamethylphosphormaide) ligands. Journal of the Chemical Society, Chemical Communications (15). pp. 974-975. ISSN 0022-4936
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
The low melting-point, hydrocabon-soluble, and moisture-sensitive crystalline material isolated from the reaction of hydrated lithium chloride with OP(NMe2)3(HMPA) has been shown by X-ray crystallography to be the discrete, internally-ionic complex, [Li·(H2O)2·HMPA]22+·2Cl–; the chloride ions are hydrogen bonded to the cations water molecules, which are terminally bonded to the lithium atoms, while the centre of the cation consists of a planar (LiO)2 ring provided by bridiging, yet formally neuttal, HMPA ligands.
| Item type: | Article |
|---|---|
| ID code: | 37489 |
| Keywords: | hexamethylphosphormaide , ligands, crystal structures, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 08 Feb 2012 15:38 |
| Last modified: | 12 Mar 2012 11:46 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/37489 |
Actions (login required)
| View Item |