Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

The isolation and crystal structure of {Li·(H2O)2·[OP(NMe2)3]}22+·2Cl–: a (LiO)2 ring compound with bridging neutral oxygen (hexamethylphosphormaide) ligands

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) The isolation and crystal structure of {Li·(H2O)2·[OP(NMe2)3]}22+·2Cl–: a (LiO)2 ring compound with bridging neutral oxygen (hexamethylphosphormaide) ligands. Journal of the Chemical Society, Chemical Communications (15). pp. 974-975. ISSN 0022-4936

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

The low melting-point, hydrocabon-soluble, and moisture-sensitive crystalline material isolated from the reaction of hydrated lithium chloride with OP(NMe2)3(HMPA) has been shown by X-ray crystallography to be the discrete, internally-ionic complex, [Li·(H2O)2·HMPA]22+·2Cl–; the chloride ions are hydrogen bonded to the cations water molecules, which are terminally bonded to the lithium atoms, while the centre of the cation consists of a planar (LiO)2 ring provided by bridiging, yet formally neuttal, HMPA ligands.

Item type: Article
ID code: 37489
Keywords: hexamethylphosphormaide , ligands, crystal structures, Chemistry, Molecular Medicine
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 08 Feb 2012 15:38
    Last modified: 05 Sep 2014 14:58
    URI: http://strathprints.strath.ac.uk/id/eprint/37489

    Actions (login required)

    View Item