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X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

BARR, D and CLEGG, W and Mulvey, Robert and SNAITH, R (1984) X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding. Journal of the Chemical Society, Chemical Communications (4). pp. 226-227. ISSN 0022-4936

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Abstract

An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.