Picture of smart phone in human hand

World leading smartphone and mobile technology research at Strathclyde...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by Strathclyde researchers from the Department of Computer & Information Sciences involved in researching exciting new applications for mobile and smartphone technology. But the transformative application of mobile technologies is also the focus of research within disciplines as diverse as Electronic & Electrical Engineering, Marketing, Human Resource Management and Biomedical Enginering, among others.

Explore Strathclyde's Open Access research on smartphone technology now...

N-heterocyclic-carbene-induced monomerization of sterically encumbered dialkylmagnesium and dialkylmanganese polymers

Kennedy, Alan and Klett, Jan and Robertson, Stuart and Mulvey, Robert (2011) N-heterocyclic-carbene-induced monomerization of sterically encumbered dialkylmagnesium and dialkylmanganese polymers. European Journal of Inorganic Chemistry (30). pp. 4675-4679. ISSN 1434-1948

Full text not available in this repository. Request a copy from the Strathclyde author


The sterically encumbered polymeric dialkyl complexes [M(CH2SiMe3)(2)](infinity) [M = Mg, Mn-II] were deaggregated by the potent two-electron sigma-donor, 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr), to yield the first examples of the monomeric three-coordinate [M(CH2SiMe3)(2)]center dot donor complexes [M = Mg (1); Mn (2)]. Similarly, monomeric three-coordinate species M[CH(SiMe3)(2)](2)center dot IPr [M = Mg, (3); Mn, (4)] were obtained from the bulkier disilyl-substituted alkyl [CH-(SiMe3)(2)] congeners M[CH(SiMe3)(2)](2)center dot ether by displacement of the ether by IPr. Complexes 1-4, which represent rare examples of N-heterocyclic-carbene-stabilized dialkylmagnesium and dialkylmanganese species, were crystallographically characterized; the diamagnetic magnesium complexes were also characterized in an arene solution by H-1 and C-13 NMR spectroscopy.