Picture of two heads

Open Access research that challenges the mind...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including those from the School of Psychological Sciences & Health - but also papers by researchers based within the Faculties of Science, Engineering, Humanities & Social Sciences, and from the Strathclyde Business School.

Discover more...

HREELS study of alkanethiol passivated gold clusters on graphite

Chen, Y. and Palmer, R.E. and Wilcoxon, J.P. (2000) HREELS study of alkanethiol passivated gold clusters on graphite. Surface Science, 454-456. pp. 963-967. ISSN 0039-6028

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Passivated metal (e.g. gold) nanoclusters consist of a metal particle core surrounded by a ligand coat. We have investigated films of gold particles passivated with alkanethiol (C8H17S) ligands deposited from solution onto a graphite surface using high-resolution electron energy loss spectroscopy (HREELS). Vibrational modes of the CH, groups of the ligands are observed, together with their overtones. Incident energy dependent measurements show an enhancement in intensity of these vibrational modes at a specific energy, similar to 10 eV, consistent with a negative ion resonance state. This observation is compared with previous studies of self-assembled monolayers of thiols on the Au (111) surface.