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The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs.

Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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Structures and optical properties of 4-5 nm bimetallic AgAu nanoparticles

Li, Z. Y. and Wilcoxon, J. P. and Yin, F. and Chen, Y. and Palmer, R. E. and Johnston, R. L. and Chen, Yu (2008) Structures and optical properties of 4-5 nm bimetallic AgAu nanoparticles. Faraday Discussions, 138. pp. 363-373. ISSN 1359-6640

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Abstract

Three types of bimetallic AgAu nanoparticles, with mean size of 4-5 nm, AgcoreAushell, AucoreAgshell and alloyed AgAu, have been synthesized using an inverse micelle method. To image these small size nanoparticles, quantitative high angle annular dark field imaging using scanning transmission electron microscopy was successfully applied. Our results show that good control of nanoparticle size dispersion and composition modulation was achieved. Optical properties of the nanoparticles are correlated with direct internal structure analysis. The structural stability is discussed, based on thermodynamic considerations.