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World class computing and information science research at Strathclyde...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by researchers from the Department of Computer & Information Sciences involved in mathematically structured programming, similarity and metric search, computer security, software systems, combinatronics and digital health.

The Department also includes the iSchool Research Group, which performs leading research into socio-technical phenomena and topics such as information retrieval and information seeking behaviour.

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Production of super selective polysulfone hollow fibre membranes for gas separation

Ismail, A.F. and Dunkin, Ian and Gallivan, S.L. and Shilton, Simon (1999) Production of super selective polysulfone hollow fibre membranes for gas separation. Polymer, 40 (23). pp. 6499-6506. ISSN 0032-3861

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Abstract

Polysulfone gas separation hollow fiber membranes were manufactured using a dry/wet spinning process with forced convection in the dry gap. Hollow fibers were produced using two different bore coagulants: one pure water and one with reduced water activity. An optimized multi-component dope was used which proved to be a shear-thinning power-law fluid. For each bore system, membranes were spun at low and high dope extrusion rates (DERs) corresponding to shear rates of around 4000 s−1 and 10 000 s−1, respectively, at the outer spinneret wall. Plane polarized infrared spectroscopy was used to probe the membrane active layer. Pressure-normalized fluxes and selectivities were evaluated using pure carbon dioxide and methane. For the spinning conditions used here, the combination of reduced water activity in the bore and high DER produced highly selective membranes. Some selectivities reached about three times the recognized intrinsic value for the polymer.