Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

On the relationship between structure and reaction rate in olefin ring-closing metathesis

Ashworth, Ian W. and Carboni, Davide and Hillier, Ian H. and Nelson, David J. and Percy, Jonathan M. and Rinaudo, Giuseppe and Vincent, Mark A. (2010) On the relationship between structure and reaction rate in olefin ring-closing metathesis. Chemical Communications, 46 (38). pp. 7145-7147. ISSN 1359-7345

[img]
Preview
PDF - Published Version
Download (1228Kb) | Preview

    Abstract

    In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously detd. showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η2-complex.

    Item type: Article
    ID code: 35058
    Notes: M1 - Copyright (C) 2011 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2010:1174696(Journal)
    Keywords: ring-closing metathesis , metathesis , cyclohexene, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
    Subjects: Science > Chemistry
    Department: Faculty of Science > Pure and Applied Chemistry
    Related URLs:
      Depositing user: Pure Administrator
      Date Deposited: 24 Oct 2011 13:40
      Last modified: 28 Mar 2014 21:11
      URI: http://strathprints.strath.ac.uk/id/eprint/35058

      Actions (login required)

      View Item

      Fulltext Downloads: