Kerr, William J. and Pazicky, Marek and McArthur, Duncan. (2008) Recyclable supported chiral amines for use within highly efficient asymmetric Mg-amide base processes. In: Asymmetric Reactions and Syntheses, 2008-08-17, Pennsylvania.
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
In 2000, our group reported on the first examples of successful deprotonations of 4-substituted cyclohexanones, using simple magnesium amide base chem., with the com. available chiral amine (R)-(+)-N-benzyl-a-methylbenzylamine. Further applications to asym. deprotonation reactions with alternative chiral base species have now been developed. In particular, new supported C2-sym. magnesium amide bases have been established. In turn, novel sol. and insol. polymers have been applied to the asym. deprotonation reaction of prochiral ketones with superb selectivity (Scheme 1). Furthermore, a supported base recycling protocol has also been developed. [on SciFinder(R)]
| Item type: | Conference or Workshop Item (Other) |
|---|---|
| ID code: | 35031 |
| Notes: | M1 - Copyright (C) 2011 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2008:954084(Conference; Meeting Abstract; Computer Optical Disk) |
| Keywords: | chiral amines , asymmetric Mg-amide base processes, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 24 Oct 2011 10:51 |
| Last modified: | 04 Oct 2012 17:51 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/35031 |
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