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Synthesis of densely branched poly(methyl methacrylates) via atom transfer radical copolymerization of MMA and EGDMA

Sherrington, David C. and Bouhier, Marc-Henri and Cormack, Peter A. G. and Graham, Susan. (2008) Synthesis of densely branched poly(methyl methacrylates) via atom transfer radical copolymerization of MMA and EGDMA. Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 49 (1). pp. 105-106. ISSN 0032-3934

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Abstract

An ATRP procedure was used to synthesize densely branched PMMAs and Ph 2-bromo-2-methylpropionate was used as the initiator, which yields primary chain ends with a specific 1H NMR spectroscopic signature.