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Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

Kennedy, Alan and Khalaf, Abedawn I. and Suckling, Colin J. and Waigh, Roger D. (2006) 3-Nitro-1-(triisopropylsilyl)-1H-pyrrole. Acta Crystallographica Section E: Structure Reports, 62 (8). o3282-o3284. ISSN 1600-5368

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Abstract

The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given.