3-Nitro-1-(triisopropylsilyl)-1H-pyrrole

Kennedy, Alan and Khalaf, Abedawn I. and Suckling, Colin J. and Waigh, Roger D. (2006) 3-Nitro-1-(triisopropylsilyl)-1H-pyrrole. Acta Crystallographica Section E: Structure Reports, 62 (8). o3282-o3284. ISSN 1600-5368 (https://doi.org/10.1107/S1600536806025943)

Full text not available in this repository.Request a copy

Abstract

The nitration of 1-(triisopropylsilyl)-1H-pyrrole leads to a mixt. of products following partial acid cleavage of the triisopropylsilyl protecting group. Structural detn. showed the isolated products to be 3-nitro-1-(triisopropylsilyl)-1H-pyrrole, C13H24N2O2Si (I), and 2,4-dinitropyrrole. In the solid state, I exists as discrete mols. with only weak C-H...nitro H bonds between them. Crystallog. data are given.