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Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

Hevia, E and Perez, J and Riera, V and Miguel, D (2002) Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N. Chemical Communications (17). pp. 1814-1815. ISSN 1359-7345

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Abstract

The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).