Picture of athlete cycling

Open Access research with a real impact on health...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the Physical Activity for Health Group based within the School of Psychological Sciences & Health. Research here seeks to better understand how and why physical activity improves health, gain a better understanding of the amount, intensity, and type of physical activity needed for health benefits, and evaluate the effect of interventions to promote physical activity.

Explore open research content by Physical Activity for Health...

Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylideneamido rhenium complexes

Cuesta, L and Hevia, E and Morales, D and Perez, J and Riera, V and Seitz, M and Miguel, D (2005) Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylideneamido rhenium complexes. Organometallics, 24 (7). pp. 1772-1775. ISSN 0276-7333

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

As an extension of previous work, the reactions of dimethylacetylenedicarboxylate (DMAD) with the phosphido complex [Re(PPh2)(CO)(3)(phen)] (1) and the alkylideneamido [Re(N=CPh2)(CO)(3)(bipy)] (2) were investigated. The characterization of the products by spectroscopy (IR and NMR) and X-ray diffraction revealed the coupling between DMAD, the phosphido or alkylideneamido group, and the phenanthroline (in the reaction of 1) or one of the carbonyl (in the reaction of 2) ligands, in a way consistent with initial attack of the P in 1 (or the N in 2) on one of the acetylenic carbons of DMAD.