Alarcon, S H and Olivieri, A C and Nordon, A and Harris, R K (1996) Solid-state electronic absorption, fluorescence and C-13 CPMAS NMR spectroscopic study of thermo- and photo-chromic aromatic Schiff bases. Journal of the Chemical Society, Perkin Transactions 2 (11). pp. 2293-2296. ISSN 1472-779XFull text not available in this repository. (Request a copy from the Strathclyde author)
Solid-state electronic absorption, fluorescence emission and C-13 CPMAS spectroscopies have been applied to a series of aromatic Schiff bases displaying both ground and excited state intramolecular proton transfer phenomena. All the results can be explained on the basis of a thermal equilibrium between enolimine and keto-enamine tautomeric forms in the crystalline state. Most of the studied compounds are thermochromic. However, a few are photochromic. The carbon-13 NMR data in the solid state show, in general, residual (C-13,N-14) dipolar coupling effects. In certain cases, however, where fast proton transfer occurs in the ground state, these effects are shown to be self-decoupled.
|Keywords:||intramolecular proton-transfer, tautomerism, optical properties , crystals, anils, N hydrogen-bonded centrosymmetric dimers, Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||21 Oct 2011 09:33|
|Last modified:||22 Mar 2017 11:44|