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Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

Kennedy, A R and Mulvey, R E and Rowlings, R B (1998) Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores. Agewandte Chemie-International Edition, 37 (22). pp. 3180-3183. ISSN 1433-7851

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Abstract

Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

Item type: Article
ID code: 34527
Keywords: alkali metals, amides, heterodimetallic compounds, oxygenations, structure elucidation, Chemistry, Chemistry(all), Catalysis
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 21 Oct 2011 09:53
    Last modified: 19 Aug 2014 13:59
    URI: http://strathprints.strath.ac.uk/id/eprint/34527

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