Spicer, Mark and Reglinski, John and Wallace, Dawn and Gibson, Lorraine (2007) [Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase. Inorganic Chemistry, 46. 3804 - 3806. ISSN 0020-1669Full text not available in this repository. (Request a copy from the Strathclyde author)
The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.
|Keywords:||sulfite oxidase , inorganic chemistry, Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||20 Oct 2011 15:36|
|Last modified:||27 Apr 2016 17:30|