Spicer, Mark and Reglinski, John and Wallace, Dawn and Gibson, Lorraine (2007) [Mo(TmMe)(O)2Cl]: an alternative functional model of sulfite oxidase. Inorganic chemistry, 46. 3804 - 3806. ISSN 0020-1669
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/ic700468m
Abstract
The hydrotris(methimazolyl)borate anion (TmMe) has been used to synthesize an alternative functional model ([Mo(TmMe)(O)2Cl]) of the metalloenzyme sulfite oxidase. It has been shown that the complex undergoes oxygen atom transfer chemistry and that it performs the primary function of the enzyme, sulfite oxidation. A method using ion chromatography has been developed to definitively prove that sulfite is oxidized to sulfate.
| Item type: | Article |
|---|---|
| ID code: | 34294 |
| Keywords: | sulfite oxidase , inorganic chemistry, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 20 Oct 2011 16:36 |
| Last modified: | 12 Mar 2012 11:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/34294 |
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