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Enhanced π···π interactions in α,β-unsaturated carbonyls

Harris, Lisa D. and Platts, James A. and Tomkinson, Nicholas C. O. (2003) Enhanced π···π interactions in α,β-unsaturated carbonyls. Organic and Biomolecular Chemistry, 1 (3). pp. 457-459. ISSN 1477-0520

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Abstract

High level ab initio calcns. on complexes of benzene with acrolein and ethene reveal that π···π interactions to electron deficient acrolein are remarkably similar to those found in the benzene dimer.