Harris, Lisa D. and Jenkins, Robert L. and Tomkinson, Nicholas C. O. (2005) The modulation of face-face π-π interactions in Lewis acid catalysis. Tetrahedron Letters, 46 (10). pp. 1627-1629. ISSN 0040-4039
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/j.tetlet.2005.01.086
Abstract
The enantiomeric excess obsd. for the exo-adduct from the Lewis acid catalyzed Diels-Alder reaction between cyclopentadiene and methacrolein can be increased up to 21% by simple modification of the electronics of the arom. ring in a series of stilbene-derived diol ligands, suggesting that the proposed face-face π-π interaction between the catalyst and the dienophile can be modulated by altering the electron d. on the arom. ring.
| Item type: | Article |
|---|---|
| ID code: | 34201 |
| Notes: | M1 - Copyright (C) 2011 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2005:130186(Journal) |
| Keywords: | methacrolein , dienophile , aromatic rings , Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Faculty of Humanities And Social Sciences > Education |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 20 Oct 2011 15:12 |
| Last modified: | 12 Mar 2012 11:35 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/34201 |
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