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Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns

Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Gemma and Robertson, Stuart (2011) Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. Angewandte Chemie, 50 (36). pp. 8375-8378. ISSN 0044-8249

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Abstract

The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).