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Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns

Kennedy, Alan and Mulvey, Robert and O'Hara, Charles and Robertson, Gemma and Robertson, Stuart (2011) Mixed lithium amide–lithium halide compounds : unusual halide-deficient amido metal anionic crowns. Angewandte Chemie, 50 (36). pp. 8375-8378. ISSN 0044-8249

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Abstract

The addition of substoichiometric quantities of lithium halides to the lithium hexamethyldisilazide was studied. Surprisingly, a novel class of mixed amido-halide macrocyclic complexes, namely metal anionic crowns (MACs) was revealed (see picture: Li pink, N yellow, Cl green, Si orange, C black).

Item type: Article
ID code: 34149
Keywords: amide–lithium halide compounds , anionic crowns, salt effect, lithium, halides, inverse crowns, Chemistry, Medicine(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 20 Oct 2011 14:10
    Last modified: 28 Mar 2014 05:42
    URI: http://strathprints.strath.ac.uk/id/eprint/34149

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