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Structure of laponite-styrene precursor dispersions for production of advanced polymer-clay nanocomposites

Fartaria, Rui and Javid, Nadeem and Pethrick, Richard and Liggat, John and Sefcik, Jan and Sweatman, Martin (2011) Structure of laponite-styrene precursor dispersions for production of advanced polymer-clay nanocomposites. Soft Matter, 7 (19). pp. 9157-9166. ISSN 1744-683X

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    One method for production of polymer-clay nanocomposites involves dispersal of surface-modified clay in a polymerisable monomeric solvent, followed by fast in situ polymerisation. In order to tailor the properties of the final material we aim to control the dispersion state of the clay in the precursor solvent. Here, we study dispersions of surface-modified Laponite, a synthetic clay, in styrene via large-scale Monte-Carlo simulations and experimentally, using small angle X-ray and static light scattering. By tuning the effective interaction between simulated laponite particles we are able to reproduce the experimental scattering intensity patterns for this system, with good accuracy over a wide range of length scales. However, this agreement could only be obtained by introducing a permanent electrostatic dipole moment into the plane of each Laponite particle, which we explain in terms of the distribution of substituted metal atoms within each Laponite particle. This suggests that Laponite dispersions, and perhaps other clay suspensions, should display some of the structural characteristics of dipolar fluids. Our simulated structures show aggregation regimes ranging from networks of long chains to dense clusters of Laponite particles, and we also obtain some intriguing ‘globular’ clusters, similar to capsids. We see no indication of any ‘house-of-cards’ structures. The simulation that most closely matches experimental results indicates that gel-like networks are obtained in Laponite dispersions, which however appear optically clear and non-sedimenting over extended periods of time. This suggests it could be difficult to obtain truly isotropic equilibrium dispersion as a starting point for synthesis of advanced polymer-clay nanocomposites with controlled structures.

    Item type: Article
    ID code: 34014
    Keywords: surface-modified clay, polymerisation, dispertion, Monte Carlo simulation, light scattering, TIC - Bionanotechnology, Physical and theoretical chemistry, Chemistry(all), Condensed Matter Physics
    Subjects: Science > Chemistry > Physical and theoretical chemistry
    Department: Faculty of Engineering > Chemical and Process Engineering
    Faculty of Science > Pure and Applied Chemistry
    Technology and Innovation Centre > Bionanotechnology
    Technology and Innovation Centre > Continuous Manufacturing and Crystallisation (CMAC)
    Related URLs:
      Depositing user: Pure Administrator
      Date Deposited: 19 Oct 2011 12:37
      Last modified: 28 Mar 2014 21:01

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