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Homo- and heteroleptic hypersilylcuprates - valuable reagents for the synthesis of molecular compounds with a Cu-Si bond

Klinkhammer, K W and Klett, J and Xiong, Y and Yao, S L (2003) Homo- and heteroleptic hypersilylcuprates - valuable reagents for the synthesis of molecular compounds with a Cu-Si bond. European Journal of Inorganic Chemistry (18). pp. 3417-3424. ISSN 1434-1948

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Abstract

Unsolvated hypersilanides MHyp [Hyp = Si(SiMe3)(3)] of the heavier alkali metals (M-I = Na, K, Cs) react with copper tert-butoxide in toluene to yield crystalline heteroleptic cuprates [M-I(toluene)][tBuOCuHyp]. These cuprates proved to be valuable sources for pure hypersilylcopper and other cuprates bearing hypersilyl ligands such as the di(hypersilyl)cuprates M-I[CuHyp(2)]((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

Item type: Article
ID code: 33996
Keywords: copper, silicon, silylcuprates, Si ligands, ray crystal-structures, cadmium, mercury, silyl, Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 18 Oct 2011 14:07
    Last modified: 05 Sep 2014 11:22
    URI: http://strathprints.strath.ac.uk/id/eprint/33996

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