Picture of a sphere with binary code

Making Strathclyde research discoverable to the world...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. It exposes Strathclyde's world leading Open Access research to many of the world's leading resource discovery tools, and from there onto the screens of researchers around the world.

Explore Strathclyde Open Access research content

Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides

Aucott, S M and Milton, H L and Robertson, S D and Slawin, A M Z and Woollins, J D (2005) Crystal structures of dibenzo[ce]-1,2-dithiine and its related oxides. Heteroatom Chemistry, 16 (5). pp. 346-351. ISSN 1042-7163

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

The X-ray structures of dibenzo[ce]-1,2dithiine, dibenzo[ce]-1,2-dithiine-5,5-dioxide, dibenzo[ce]-1,2-dithiine-5,5,6-trioxide, and dibenzo[ce]-1, 2-dithiine-5,5,6,6-tetraoxide are reported and compared with the related "constrained" naphthalene derivatives. The S-S distances vary upon oxidation of the S centers in the order S-S < SO-S > SO2-S < SO2-SO > SO2-SO2 i.e. the most oxidized sulfur atoms do not lead to the longest bond lengths.