Conway, Ben and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Robertson, Stuart D. (2010) Structural insights into mono-amido tris-alkyl potassium aluminates. New Journal of Chemistry, 34 (8). pp. 1707-1712. ISSN 1144-0546Full text not available in this repository. (Request a copy from the Strathclyde author)
Co-complexation of a potassium amide with (Bu3Al)-Bu-i in the presence of the tridentate chelating ligand PMDETA results in a series of potassium aluminates of general formula [PMDETA center dot K(mu-amide)(mu-Bu-i)Al(Bu-i)(2)] [where amide = TMP (6); DMP (7); HMDS (8)] which have been characterized by solution NMR spectroscopy and X-ray crystallography. Their solid-state structures contain a central KNAlC ring whose degree of puckering is dictated by the differing interactions between the potassium centre and the aluminium bound anionic ligands.
|Keywords:||directed ortho metalation, tertiary aromatic amide, pyrimidines, mediated magnesiation, functionalizations, Physical and theoretical chemistry, Materials Chemistry, Chemistry(all), Catalysis|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Pure Administrator|
|Date Deposited:||19 Oct 2011 04:20|
|Last modified:||22 Mar 2017 11:39|