Picture of a sphere with binary code

Making Strathclyde research discoverable to the world...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. It exposes Strathclyde's world leading Open Access research to many of the world's leading resource discovery tools, and from there onto the screens of researchers around the world.

Explore Strathclyde Open Access research content

Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Carrella, Luca M. and Foerster, Christoph and Kennedy, Alan R. and Klett, Jan and Mulvey, Robert E. and Rentschler, Eva (2010) Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges. Organometallics, 29 (21). pp. 4756-4758. ISSN 0276-7333

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.