Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

Garcia, Felipe and Less, Robert J. and McPartlin, Mary and Michalski, Annette and Mulvey, Robert E. and Naseri, Vesal and Stead, Matthew L. and de Vega, Ana Moran and Wright, Dominic S. (2011) Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity. Chemical Communications (London), 47 (6). pp. 1821-1823. ISSN 0009-241X (https://doi.org/10.1039/c0cc04483k)

Abstract

The structures of a series of spherical host-guest complexes [{MeE(PPh)(3)Li-4 center dot 3thf}(4)(mu(4)-X)](-) (E = Al, [1X](-); E = Ga, [2X](-); E = In, [3X](-)) reveal that changing the halide ions (X = Cl, Br, or I) within their central tetrahedral Li-4 sites has negligible effect on the structural parameters.

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• Item metadata

  Item type:	Article
  ID code:	33791
  Dates:	Date Event 2011 Published 6 December 2010 Published Online
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	16 Oct 2011 15:07
  Last modified:	08 Apr 2024 19:26
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/33791