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The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including those from the School of Psychological Sciences & Health - but also papers by researchers based within the Faculties of Science, Engineering, Humanities & Social Sciences, and from the Strathclyde Business School.

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Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures

Craig, F J and Kennedy, A R and Mulvey, R E and Spicer, M D (1996) Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures. Chemical Communications (London) (16). pp. 1951-1952. ISSN 0009-241X

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Abstract

Equimolar mixtures of AlMe(3), Bu(t)OK, and pmdeta produce either title compound depending on whether solvent-free, dimeric [(AlMe(3))(2)] or the amine-solvated monomer [Me(3)Al .(H)N(CH(2)Ph)(2)] is used as the source of the alane.