Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/c0cc02164d
Abstract
The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).
| Item type: | Article |
|---|---|
| ID code: | 33729 |
| Keywords: | trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 18 Oct 2011 11:56 |
| Last modified: | 04 Oct 2012 13:53 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/33729 |
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