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Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Baillie, Sharon E. and Clegg, William and Garcia-Alvarez, Pablo and Hevia, Eva and Kennedy, Alan R. and Klett, Jan and Russo, Luca (2011) Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate. Chemical Communications (London), 47 (1). pp. 388-390. ISSN 0009-241X

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Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

Item type: Article
ID code: 33729
Keywords: trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate, Physical and theoretical chemistry, Chemistry(all)
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 18 Oct 2011 11:56
Last modified: 05 Sep 2014 11:08
URI: http://strathprints.strath.ac.uk/id/eprint/33729

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