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Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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Azafulvenium methides : new extended dipolar systems

Sutcliffe, O B and Storr, R C and Gilchrist, T L and Rafferty, P and Crew, A P A (2000) Azafulvenium methides : new extended dipolar systems. Chemical Communications (London) (8). pp. 675-676. ISSN 0009-241X

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Abstract

The transient 8 pi 1,7-dipolar azafulvenium methides 5 and 8 undergo sigmatropic [1,8] H shifts and the acyl derivatives 12 electrocyclise to give novel pyrrolooxazines 13; the related diazafulvenium methide 15 can be intercepted in 8 pi + 2 pi cycloadditions with silylated acetylenes.