Bain, James Roderic Peter and Johnstone, Walter and Ruxton, Keith Crawford and Stewart, George and Lengden, Michael and Duffin, Kevin (2011) Recovery of absolute gas absorption line shapes using tunable diode laser spectroscopy with wavelength modulation - Part 2 : experimental investigation. Journal of Lightwave Technology, 29 (7). pp. 987-996. ISSN 0733-8724Full text not available in this repository. (Request a copy from the Strathclyde author)
Recovery of absolute gas absorption line-shapes from 1st harmonic residual amplitude modulation (RAM) signals in tuneable diode laser spectroscopy with wavelength modulation (TDLS-WM) offers significant advantages in terms of measurement accuracy (for gas concentration and pressure), freedom from the need for calibration and resilience to errors or drift in system parameters / scaling factors. However, the signal strength and signal to noise ratio are compromised somewhat relative to conventional wavelength modulation spectroscopy (WMS) by the signal dependency on the laser’s intensity modulation amplitude rather than on the direct intensity, and by the need to operate at low modulation index, m (<0.75), in the previously reported work. In Part 1 of this two part publication, we report a more universal approach to the analysis of recovered RAM signals and absolute absorption line-shapes. This new approach extends the use of RAM techniques to arbitrary m values up to 2.2. In addition, it provides the basis for a comparison of signal strength between the RAM signals recovered by the phasor decomposition approach and conventional 1st and 2nd harmonic TDLS-WM signals. The experimental work reported here validates the new model and demonstrates the use of the RAM techniques for accurate recovery of absolute gas absorption line-shapes to m = 2.2 and above. Furthermore, it demonstrates that the RAM signal strengths can be increased significantly by increasing the modulation frequency and defines regimes of operation such that the directly recovered RAM signals are comparable to or even greater than the widely used, conventional 2nd harmonic TDLS-WM signal. Finally, a critique of the RAM techniques relative to the conventional approaches is given.
|Keywords:||absorption line-shape recovery, diode laser spectroscopy, gas sensors, industrial and environmental monitoring, wavelength modulation spectroscopy, frequency modulation, random access , harmonic analysis, resonant frequency , Electrical engineering. Electronics Nuclear engineering|
|Subjects:||Technology > Electrical engineering. Electronics Nuclear engineering|
|Department:||Faculty of Engineering > Electronic and Electrical Engineering|
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|Depositing user:||Pure Administrator|
|Date Deposited:||23 Jun 2011 10:05|
|Last modified:||14 Jun 2013 16:23|
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