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Effect of activated carbon xerogel pore size on the capacitance performance of ionic liquid electrolytes

Sillars, Fiona. B. and Fletcher, S. Isobel and Mirzaeian, Mojtaba and Hall, Peter J. (2011) Effect of activated carbon xerogel pore size on the capacitance performance of ionic liquid electrolytes. Energy & Environmental Science, 4 (3). pp. 695-706. ISSN 1754-5692

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Abstract

The use of ionic liquid (IL) electrolytes promises to improve the energy density of electrochemical capacitors (ECs) by allowing for operation at higher voltages. Several studies have also shown that the pore size distribution of materials used to produce electrodes is an important factor in determining EC performance. In this research the capacitative, energy and power performance of ILs 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF(4)), 1-ethyl-3-methylimidazolium dicyanamide (EMImN(CN)(2)), 1,2-dimethyl-3-propylimidazolium bis(trifluoromethylsulfonyl)imide (DMPImTFSI), and 1-butyl-3-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate (BMPyT(F5Et)PF3) were studied and compared with the commercially utilised organic electrolyte 1M tetraethylammonium tetrafluoroborate solution in anhydrous propylene carbonate (Et4NBF4-PC 1 M). To assess the effect of pore size on IL performance, controlled porosity carbons were produced from phenolic resins activated in CO2. The carbon samples were characterised by nitrogen adsorption-desorption at 77 K and the relevant electrochemical behaviour was characterised by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The best capacitance performance was obtained for the activated carbon xerogel with average pore diameter 3.5 nm, whereas the optimum rate performance was obtained for the activated carbon xerogel with average pore diameter 6 nm. When combined in an EC with IL electrolyte EMImBF(4) a specific capacitance of 210 F g(-1) was obtained for activated carbon sample with average pore diameter 3.5 nm at an operating voltage of 3 V. The activated carbon sample with average pore diameter 6 nm allowed for maximum capacitance retention of approximately 70% at 64 mA cm(-2).

Item type: Article
ID code: 31651
Keywords: double-layer capacitors, physicochemical properties, aerogel electrodes, mesoporous carbons, porous carbon, supercapacitor, resorcinol, Chemical engineering, Environmental Chemistry, Pollution, Nuclear Energy and Engineering, Renewable Energy, Sustainability and the Environment
Subjects: Technology > Chemical engineering
Department: Faculty of Engineering > Chemical and Process Engineering
Related URLs:
Depositing user: Pure Administrator
Date Deposited: 15 Jun 2011 14:28
Last modified: 27 Mar 2014 09:25
URI: http://strathprints.strath.ac.uk/id/eprint/31651

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