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On the role(s) of additives in bioinspired silicification

Patwardhan, S V and Clarson, S J and Perry, C C (2005) On the role(s) of additives in bioinspired silicification. Chemical Communications (London) (9). pp. 1113-1121. ISSN 0009-241X

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Abstract

Biological organisms are able to direct the formation of patterned and hierarchical biomineral structures. Extractable organic materials have been found entrapped in diatom, sponge and plant biosilica, some of which have been isolated by selective chemical dissolution methods and their composition and structure studied. Information gained from the bioextracts has inspired materials chemists to design biomimetic analogues and develop bioinspired synthetic schemes for silica formation. The results obtained from bioinspired silicification investigations are hypothesised to arise from specific modes of action of the organic additives, which are described in this review. Specifically, additives in bioinspired silicification act either as catalysts, aggregation promoting agents or structure-directing agents or more typically, exhibit a combination of these behaviours.

Item type: Article
ID code: 31557
Keywords: si-29 nmr shifts, silica structures, mesoporous silica, colloidal silica, diatom frustule, organic matrix, amino acids , complexes, biosilification, Chemical engineering
Subjects: Technology > Chemical engineering
Department: Faculty of Engineering > Chemical and Process Engineering
Related URLs:
    Depositing user: Pure Administrator
    Date Deposited: 15 Jun 2011 12:43
    Last modified: 17 Jul 2013 10:35
    URI: http://strathprints.strath.ac.uk/id/eprint/31557

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