Fuller, A M and Leigh, D A and Lusby, P J and Oswald, I D H and Parsons, S and Walker, D B (2004) A 3D interlocked structure from a 2D template : structural requirements for the assembly of a square-planar metal-coordinated [2]rotaxane. Agewandte Chemie-International Edition, 43 (30). pp. 3914-3918. ISSN 1433-7851
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/anie.200353622
Abstract
The synthesis of a three-dimensional interlocked molecular architecture (a rotaxane) from a two-dimensional square-planar metal template (see scheme) has been achieved. A combination of steric and electronic factors direct the synthesis in the third dimension, either by promoting or preventing interlocking.
| Item type: | Article |
|---|---|
| ID code: | 31368 |
| Keywords: | coordination modes, palladium, rotaxanes, template synthesis, transition-metal, incorporating cucurbituril, thermodynamic control, crystal-structures, rotaxanes, complexes, bonds, refinement, catenanes, molecules, Pharmacy and materia medica |
| Subjects: | Medicine > Pharmacy and materia medica |
| Department: | Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences |
| Related URLs: | |
| Depositing user: | Pure Administrator |
| Date Deposited: | 13 Jul 2011 09:56 |
| Last modified: | 12 Mar 2012 11:27 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/31368 |
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