Picture of two heads

Open Access research that challenges the mind...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including those from the School of Psychological Sciences & Health - but also papers by researchers based within the Faculties of Science, Engineering, Humanities & Social Sciences, and from the Strathclyde Business School.

Discover more...

pH tracking of silica hydrogel nanoparticle growth

Cleary, Alison and Karolin, Jan and Birch, David J. S. (2006) pH tracking of silica hydrogel nanoparticle growth. Applied Physics Letters, 89 (11). p. 113125. ISSN 0003-6951

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

The authors show that pH increase, due to removal by condensation of silicic acid, correlates with nanoparticle growth during the initial stages of silica hydrogel formation and becomes constant at a time t(pH), the point when other particle growth mechanisms dominate. Absorption of common phthalein indicators is shown to allow effectively instantaneous tracking of the pH and nanoparticle size in alkaline and acidic hydrogels. Particle sizes are calibrated using the hydrodynamic radius determined from the fluorescence anisotropy decay. Tracking pH complements fluorescence anisotropy nanometrology by offering a lower cost, speedier, and simpler method of studying particle growth during silica hydrogel fabrication. (c) 2006 American Institute of Physics.