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The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs.

Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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Real-time trace-level detection of carbon dioxide and ethylene in car exhaust gases

McCulloch, M T and Langford, N and Duxbury, G (2005) Real-time trace-level detection of carbon dioxide and ethylene in car exhaust gases. Applied Optics, 44 (14). pp. 2887-2894. ISSN 1559-128X

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Abstract

A direct-absorption spectrometer, based on a pulsed, distributed feedback, quantum cascade laser with a 10.26-μ m wavelength and an astigmatic Herriott cell with a 66-m path length, has been developed for high-resolution IR spectroscopy. This spectrometer utilizes the intrapulse method, an example of sweep integration, in which the almost linear wavelength up-chirp obtained from a distributed feedback, quantum cascade laser yields a spectral microwindow of as many as 2.5 wave numbers/cm(-1). Within this spectral microwindow, molecular fingerprints can be monitored and recorded in real time. This system allows both the detection of carbon dioxide and ethylene and the real-time observation of the evolution of these gases in the exhaust by-products from several cars. © 2005 Optical Society of America.