Karolin, J. and Geddes, C.D. and Wynne, Klaas and Birch, D.J.S. (2001) Nanoparticle metrology in sol-gels using multiphoton excited fluorescence. Measurement Science and Technology, 13 (1). pp. 21-27. ISSN 0957-0233Full text not available in this repository. (Request a copy from the Strathclyde author)
We have developed a method of measuring the growth of nanoparticles during sol-gel glass formation based on labelling the particle with a fluorescent dye and determining the multiphoton excited decay of fluorescence anisotropy due to Brownian rotation. Multiphoton excitation is shown to give a higher dynamic range of measurement than one-photon excitation. We illustrate the sub-nanometre resolution and stability of our approach by detecting a 0.8-1.1 nm silica particle hydrodynamic mean radius increase in a tetramethylorthosilicate sol at pH 2.3 labelled with rhodamine 6G and observed over ≈4 weeks and also with a stable silica colloid of radius 6 nm, pH 8.9, labelled with a 6-methoxyquinoline-type dye.
|Keywords:||particle metrology, fluorescence anisotropy decay, multiphoton excitation, sol-gel, TMOS, nanoscience, Solid state physics. Nanoscience, Instrumentation, Applied Mathematics|
|Subjects:||Science > Physics > Solid state physics. Nanoscience|
|Department:||Faculty of Science > Physics|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||15 Feb 2007|
|Last modified:||29 Apr 2016 07:24|