Macleod, Fraser and Lang, Stuart and Murphy, J.A. (2010) The 2-(2-Azidoethyl)cycloalkanone strategy for bridged amides and medium-sized cyclic amine derivatives in the Aubé-Schmidt reaction. Synlett, 2010 (4). pp. 529-534. ISSN 0936-5214
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Official URL: http://dx.doi.org/10.1055/s-0029-1219340
Abstract
2-(2-Azidoethyl)cycloalkanones afford bridged lactams in the Aubé-Schmidt reaction, sometimes in excellent yield, and solvolysis yields derivatives of medium-ring amines. Attempts to divert the Schmidt reaction with an arene-mediated fragmentation of the normal Schmidt intermediate have led to an initial example
| Item type: | Article |
|---|---|
| ID code: | 28352 |
| Keywords: | Aubé, Schmidt, rearrangement, azide, heterocycle, bridged amide, medium-ring amine, medium-ring amide, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Ms Carol Khalaf |
| Date Deposited: | 13 May 2011 09:45 |
| Last modified: | 13 Apr 2013 13:16 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/28352 |
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