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Analytical solution of the proper integral-equations for interaction site fluids

Lue, L. and Blankschtein, D. (1995) Analytical solution of the proper integral-equations for interaction site fluids. Journal of Chemical Physics, 103 (3). pp. 1229-1231. ISSN 0021-9606

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We apply the Wiener-Hopf factorization technique to the Chandler-Silbey-Ladanyi equations with the Percus-Yevick closure for a general fluid composed of hard-sphere interaction sites. We analytically solve these equations for symmetric n- atomic tangent hard-sphere molecules (n less than or equal to 4), and obtain closed analytical expressions for the equation of stare and other thermodynamic properties of the fluid.

Item type: Article
ID code: 27957
Notes: English Note RJ371 J CHEM PHYS
Keywords: diatomics, integral equations, analytical solution, hard−sphere model, equations of state, thermodynamic properties, liquid structure, Physical and theoretical chemistry, Physics and Astronomy(all), Physical and Theoretical Chemistry
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Engineering > Chemical and Process Engineering
Depositing user: Dr Leo Lue
Date Deposited: 14 Oct 2010 17:25
Last modified: 21 May 2015 12:16

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