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Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation

Mulvey, R.E. and Kennedy, A.R. and Hevia, E. (2007) Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation. Chemical Communications (London) (27). pp. 2864-2866. ISSN 0009-241X

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Abstract

Demonstrating direct synergic ''low polarity metallation'', 1-methylindole is C-magnesiated by (TMEDA)2?Na2MgBu4 and C-zincated by (TMEDA)?Na(tBu)(TMP)Zn(tBu), and 1-methylpyrrole is C-zincated by the same reagent, with all three metal products successfully crystallographically characterised.

Item type: Article
ID code: 27773
Keywords: aromatic compounds, low polarity metallation, Physical and theoretical chemistry, Chemistry(all)
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Miss Stephanie Cassidy
    Date Deposited: 11 Oct 2010 20:02
    Last modified: 28 Mar 2014 05:23
    URI: http://strathprints.strath.ac.uk/id/eprint/27773

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