Mulvey, R.E. and Kennedy, A.R. and Hevia, E. (2007) Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation. Chemical Communications (London) (27). pp. 2864-2866. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http:/dx.doi.org/10.1039/b704362g
Abstract
Demonstrating direct synergic ''low polarity metallation'', 1-methylindole is C-magnesiated by (TMEDA)2?Na2MgBu4 and C-zincated by (TMEDA)?Na(tBu)(TMP)Zn(tBu), and 1-methylpyrrole is C-zincated by the same reagent, with all three metal products successfully crystallographically characterised.
| Item type: | Article |
|---|---|
| ID code: | 27773 |
| Keywords: | aromatic compounds, low polarity metallation, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Miss Stephanie Cassidy |
| Date Deposited: | 11 Oct 2010 20:02 |
| Last modified: | 04 Oct 2012 13:19 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/27773 |
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