Mulvey, R.E. and Mongin, F. and Uchiyama, M. and Kondo, Y. (2007) Deprotonative metalation using ate compounds: synergy, synthesis, and structure building. Angewandte Chemie, 46 (21). pp. 3802-3824. ISSN 0044-8249Full text not available in this repository. (Request a copy from the Strathclyde author)
Historically, single-metal organometallic species such as organolithium compounds have been the reagents ofch oice in synthetic organic chemistry for performing deprotonation reactions. Over the past few years, a complementary new class of metalating agents has started to emerge. Owing to a variable central metal (magnesium, zinc, or aluminum), variable ligands (both in their nature and number), and a variable second metallic center (an alkali metal such as lithium or sodium), 'ate' complexes are highly versatile bases that exhibit a synergic chemistry which cannot be replicated by the homometallic magnesium, zinc, or aluminum compounds on their own. Deprotonation accomplished by using these organometallic ate complexes has opened up new perspectives in organic chemistry with unprecedented reactivities and sometimes unusual and unpredictable regioselectivities.
|Keywords:||ate complexes, dimetallic complexes, inverse crown compounds, metalation, synthetic methods, Physical and theoretical chemistry, Medicine(all)|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Miss Stephanie Cassidy|
|Date Deposited:||11 Oct 2010 19:18|
|Last modified:||17 Feb 2017 04:40|