Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Hevia, E. and Garcia Alvarez, Joaquin (2007) Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane. Chemical Communications (London) (23). pp. 2402-2404. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b700785j
Abstract
Three Lewis base variations of the synthetically useful aluminate [L?Li(TMP)(iBu)Al(iBu)2], where L is TMPH, Et3N or PhC(LO)NiPr2, are reported, together with the reaction of the benzamide complex with 1,4-dioxane, which surprisingly leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.
| Item type: | Article |
|---|---|
| ID code: | 27771 |
| Keywords: | Lewis base aluminate, TMP aluminate, 4-dioxane, benzamide complex, Physical and theoretical chemistry |
| Subjects: | Science > Chemistry > Physical and theoretical chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Miss Stephanie Cassidy |
| Date Deposited: | 11 Oct 2010 20:39 |
| Last modified: | 25 Apr 2012 12:34 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/27771 |
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