Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Hevia, E. and Garcia Alvarez, Joaquin (2007) Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane. Chemical Communications (London) (23). pp. 2402-2404. ISSN 0009-241XFull text not available in this repository. (Request a copy from the Strathclyde author)
Three Lewis base variations of the synthetically useful aluminate [L?Li(TMP)(iBu)Al(iBu)2], where L is TMPH, Et3N or PhC(LO)NiPr2, are reported, together with the reaction of the benzamide complex with 1,4-dioxane, which surprisingly leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.
|Keywords:||Lewis base aluminate, TMP aluminate, 4-dioxane, benzamide complex, Physical and theoretical chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry > Physical and theoretical chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Miss Stephanie Cassidy|
|Date Deposited:||11 Oct 2010 19:39|
|Last modified:||27 Apr 2016 15:32|