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Thermal degradation studies of polyurethane/POSS nanohybrid elastomers

Lewicki, James P. and Pielichowski, Krzysztof and De la Croix, Pauline Tremblot and Janowski, Bartlomiej and Todd, Deborah and Liggat, John J. (2010) Thermal degradation studies of polyurethane/POSS nanohybrid elastomers. Polymer Degradation and Stability, 95 (6). pp. 1099-1105. ISSN 0141-3910

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    Abstract

    Reported here is the synthesis of a series of polyurethane/POSS nanohybrid elastomers, the characterisation of their thermal stability and degradation behaviour at elevated temperatures using a combination of thermogravimetric Analysis (TGA) and thermal volatilisation analysis (TVA). A series of PU elastomer systems have been formulated incorporating varying levels of 1,2-propanediol-heptaisobutyl-POSS (PHIPOSS) as a chain extender unit, replacing butane diol. The bulk thermal stability of the nanohybrid systems has been characterised using TGA. Results indicate that covalent incorporation of POSS into the PU elastomer network increases the non-oxidative thermal stability of the systems. TVA analysis of the thermal degradation of the POSS/PU hybrid elastomers have demonstrated that the hybrid systems are indeed more thermally stable when compared to the unmodified PU matrix; evolving significantly reduced levels of volatile degradation products and exhibiting an approximately 30 °C increase in onset degradation temperature. Furthermore, characterisation of the distribution of degradation products from both unmodified and hybrid systems indicate that the inclusion of POSS in the PU network is directly influencing the degradation pathways of both the soft and hard-block components of the elastomers: The POSS/PU hybrid systems show reduced levels of CO, CO2, water and increased levels of THF as products of thermal degradation.

    Item type: Article
    ID code: 27713
    Keywords: polyurethane, POSS, thermal degradation, elastomer, Physical and theoretical chemistry, Materials Chemistry, Polymers and Plastics, Mechanics of Materials, Condensed Matter Physics
    Subjects: Science > Chemistry > Physical and theoretical chemistry
    Department: Faculty of Science > Pure and Applied Chemistry
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    Depositing user: Mrs Roslyn MacDonald
    Date Deposited: 06 Oct 2010 17:21
    Last modified: 27 Mar 2014 09:06
    URI: http://strathprints.strath.ac.uk/id/eprint/27713

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