Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Structure and ionic conductivity in lithium garnets

Cussen, E.J. (2010) Structure and ionic conductivity in lithium garnets. Journal of Materials Chemistry, 20. pp. 5167-5173. ISSN 0959-9428

This is the latest version of this item.

[img]
Preview
PDF (strathprints027561.pdf)
strathprints027561.pdf

Download (344kB) | Preview
[img] Microsoft Word (EJCussen_B925553B_Text.doc)
EJCussen_B925553B_Text.doc

Download (162kB)
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_1.tif)
Cussen_B925553B_Fig_1.tif

Download (423kB) | Preview
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_2.tif)
Cussen_B925553B_Fig_2.tif

Download (951kB) | Preview
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_3.tif)
Cussen_B925553B_Fig_3.tif

Download (611kB) | Preview
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_4.tif)
Cussen_B925553B_Fig_4.tif

Download (410kB) | Preview
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_5.tif)
Cussen_B925553B_Fig_5.tif

Download (269kB) | Preview
[img]
Preview
Image (TIFF) (Cussen_B925553B_Fig_6.tif)
Cussen_B925553B_Fig_6.tif

Download (1MB) | Preview

Abstract

Garnets are capable of accommodating an excess of lithium cations beyond that normally found in this prototypical structure. This excess lithium is found in a mixture of coordination environments with considerable positional and occupational disorder and leads to ionic conductivity of up to 4×10-4 S cm-1 at room temperature. This high value for total conductivity, combined with excellent thermal and (electro)chemical resistance makes these candidate materials for operation in all solid-state batteries. This review looks at garnets with a wide range of stoichiometries and lithium concentrations and the impact of complex lithium distributions and crystallographic order/disorder transitions on the transport properties of these materials.

Item type: Article
ID code: 27696
Keywords: materials science, ionic conductivity, lithium garnets, Physical and theoretical chemistry, Materials Chemistry, Chemistry(all)
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Mrs Roslyn MacDonald
Date Deposited: 06 Oct 2010 18:56
Last modified: 26 Mar 2015 20:13
URI: http://strathprints.strath.ac.uk/id/eprint/27696

Available Versions of this Item

Actions (login required)

View Item View Item