Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

Mulvey, R.E. and Naseri, Vasel and Less, R.J. and McPartlin, Mary and Wright, Dominic S. (2010) Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. Chemical Communications (London), 46 (27). pp. 5000-5002. ISSN 0009-241X (http://dx.doi.org/10.1039/C0CC00827C)

Abstract

The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

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• Item metadata

  Item type:	Article
  ID code:	27638
  Dates:	Date Event 2010 Published
  Subjects:	Science > Chemistry > Physical and theoretical chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mrs Gillian Neeson
  Date deposited:	08 Oct 2010 19:51
  Last modified:	08 Apr 2024 18:31
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/27638