Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

Mulvey, R.E. and Kennedy, A.R. and Klett, J. and Garcia-Alvarez, P. (2010) Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations. Dalton Transactions, 39. pp. 62-65. ISSN 1472-7773

[img]
Preview
PDF (strathprints027630.pdf)
strathprints027630.pdf

Download (540kB) | Preview

Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA.K(μ-TMP)(μ-Me)Zn(Me)] produces the monozincated complexes [{PMDETA.K(μ-Me)2Zn(Fc)}∞] and [{PMDETA.K(μ-Me)2Zn(Rc)}2] respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

Item type: Article
ID code: 27630
Keywords: potassium-mediated zincation, ferrocene, ruthenocene, potassium, supramolecular variations, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Mrs Gillian Neeson
Date Deposited: 05 Oct 2010 14:14
Last modified: 21 May 2015 12:42
Related URLs:
URI: http://strathprints.strath.ac.uk/id/eprint/27630

Actions (login required)

View Item View Item