Mulvey, R.E. and Kennedy, A.R. and Klett, J. and O'Hara, C.T. (2010) Structural elaboration of the surprising ortho-zincation of benzylmethylether. Chemical Communications (London), 46. pp. 2319-2321. ISSN 0009-241X
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Official URL: http://dx.doi.org/10.1039/b924791b
Abstract
Breaking with convention, the reaction of the sodium zincate, [(TMEDA)Na(μ-TMP)(μ-tBu)Zn(tBu)] with benzyl methyl ether (PhCH2OMe) produces exclusively an ortho-zincated intermediate [(TMEDA)Na(μ-TMP)(μ-C6H4CH2OMe)Zn(tBu)] instead of the expected 'thermodynamic' α-metallated product.
| Item type: | Article |
|---|---|
| ID code: | 27629 |
| Keywords: | ortho-zincation, benzylmethylether, chemistry, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Mrs Gillian Neeson |
| Date Deposited: | 05 Oct 2010 15:36 |
| Last modified: | 06 Oct 2012 09:02 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/27629 |
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