Picture of smart phone in human hand

World leading smartphone and mobile technology research at Strathclyde...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by Strathclyde researchers from the Department of Computer & Information Sciences involved in researching exciting new applications for mobile and smartphone technology. But the transformative application of mobile technologies is also the focus of research within disciplines as diverse as Electronic & Electrical Engineering, Marketing, Human Resource Management and Biomedical Enginering, among others.

Explore Strathclyde's Open Access research on smartphone technology now...

Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities

Armstrong, David R. and Garcia-Álvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Parkinson, John A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie International Edition, 49 (18). 3185–3188. ISSN 1433-7851

[img]
Preview
Text (Armstrong-etal-ACIE2010-Diisopropylamide-and-TMP-turbo-grignard-reagents)
Armstrong_etal_ACIE2010_Diisopropylamide_and_TMP_turbo_grignard_reagents.pdf - Accepted Author Manuscript

Download (5MB) | Preview

Abstract

A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.