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Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities

Armstrong, D.R. and Garcia-Alvarez, P. and Kennedy, A.R. and Mulvey, R.E. and Parkinson, J.A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie International Edition, 49 (18). 3185–3188. ISSN 1433-7851

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    Abstract

    A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent '(iPr2N)MgCl⋅LiCl' (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies.

    Item type: Article
    ID code: 27619
    Keywords: amides, grignard reagents, metalation, structure elucidation, DOSY NMR spectroscopy, Chemistry, Chemistry(all)
    Subjects: Science > Chemistry
    Department: Faculty of Science > Pure and Applied Chemistry
    Related URLs:
    Depositing user: Mrs Gillian Neeson
    Date Deposited: 04 Oct 2010 16:31
    Last modified: 28 Mar 2014 10:34
    URI: http://strathprints.strath.ac.uk/id/eprint/27619

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