Conway, B. and Kennedy, A.R. and Mulvey, R.E. and Robertson, Stuart D. and Garcia Alvarez, Joaquin (2010) Structurally stimulated deprotonation/alumination of the TMP anion. Angewandte Chemie, 49 (18). pp. 3182-3184. ISSN 0044-8249
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/anie.201000181
Abstract
Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.
| Item type: | Article |
|---|---|
| ID code: | 27616 |
| Keywords: | alkali metals, aluminium, amides, metalation, steric effects, Science (General), Chemistry |
| Subjects: | Science > Science (General) Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Mrs Gillian Neeson |
| Date Deposited: | 13 May 2011 09:41 |
| Last modified: | 19 Sep 2012 16:48 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/27616 |
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