Wallace, Dawn and Quinn, Edward John and Armstrong, David and Reglinski, J. and Spicer, M.D. and Smith, W.E. (2010) Surface science of soft scorpionates. Inorganic Chemistry, 49 (4). pp. 1420-1427. ISSN 0020-1669Full text not available in this repository. (Request a copy from the Strathclyde author)
The chemisorption of the soft scorpionate Li[PhTmMe] onto silver and gold surfaces is reported. Surface enhanced Raman spectroscopy in combination with the Raman analysis of suitable structural models, namely, [Cu(κ3-S,S,S-PhTmMe)(PCy3)], [Ag(κ3-S,S,S-PhTmMe)(PCy3)], [Ag(κ2-S,S-PhTmMe)(PEt3)], and [Au(κ1-S-PhTmMe)(PCy3)], are employed to identify the manner in which this potentially tridentate ligand binds to these surfaces. On colloidal silver surface-enhanced Raman spectroscopy (SERS) spectra are consistent with PhTmMe binding in a didentate fashion to the surface, holding the aryl group in close proximity to the surface. In contrast, on gold colloid, we observe that the species prefers a monodentate coordination in which the aryl group is not in close proximity to the surface.
|Keywords:||scorpionates, inorganic chemistry, chemisorption, spectroscopy, Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Mrs Gillian Neeson|
|Date Deposited:||01 Oct 2010 15:41|
|Last modified:||27 Apr 2016 15:56|