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Regioselective Pauson-Khand processes with olefins possessing extended phosphonates

Kedzia, J.L. and Kerr, W.J. and McPherson, A.R. (2010) Regioselective Pauson-Khand processes with olefins possessing extended phosphonates. Synlett, 2010 (4). pp. 649-653. ISSN 0936-5214

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Abstract

Olefins possessing tethered -functionalised phosphonate functionality have been shown to be effective cyclisation partners within intermolecular Pauson-Khand processes. The optimised protocol described facilitates intermolecular cyclisations with high levels of olefinic regiocontrol.

Item type: Article
ID code: 27524
Keywords: alkyne complexes, annulations, functionalised phosphonates, Pauson-Khand reaction, regioselectivity, Chemistry, Organic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Ms Carol Khalaf
Date Deposited: 13 May 2011 10:14
Last modified: 27 Mar 2014 09:02
URI: http://strathprints.strath.ac.uk/id/eprint/27524

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