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Structural similarities of 2-chlorophenol and 2-methylphenol

Oswald, I.D.H. and Crichton, W.A. (2009) Structural similarities of 2-chlorophenol and 2-methylphenol. CrystEngComm, 11. pp. 463-469. ISSN 1466-8033

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Abstract

Investigation of 2-methylphenol and 2-chlorophenol reveals similarities in structure at both low temperature and high pressure. Co-crystallisation of the two components results in the formation of a 0.45:0.55 2-methylphenol:2-chlorophenol co-crystal at low temperature but at high pressure the mixture is separated resulting in the formation of a new polymorph of 2-chlorophenol.