Picture of athlete cycling

Open Access research with a real impact on health...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the Physical Activity for Health Group based within the School of Psychological Sciences & Health. Research here seeks to better understand how and why physical activity improves health, gain a better understanding of the amount, intensity, and type of physical activity needed for health benefits, and evaluate the effect of interventions to promote physical activity.

Explore open research content by Physical Activity for Health...

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate

Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

In a new type of reactivity for sodium TMP-zincate [(TMEDA) NaZn(Bu-t)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).